<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">hydrophysics</journal-id><journal-title-group><journal-title xml:lang="ru">Фундаментальная и прикладная гидрофизика</journal-title><trans-title-group xml:lang="en"><trans-title>Fundamental and Applied Hydrophysics</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2073-6673</issn><issn pub-type="epub">2782-5221</issn><publisher><publisher-name>St. Petersburg Research Center of the Russian Academy of Sciences</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.59887/2073-6673.2023.16(4)-8</article-id><article-id custom-type="elpub" pub-id-type="custom">hydrophysics-1261</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ГИДРОФИЗИЧЕСКИЕ И БИОГЕОХИМИЧЕСКИЕ ПОЛЯ И ПРОЦЕССЫ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>HYDROPHYSICAL AND BIOGEOCHEMICAL FIELDS AND PROCESSES</subject></subj-group></article-categories><title-group><article-title>Некоторые замечания о фазовом превращении газогидратов в пористых осадках при отрицательной по Цельсию температуре</article-title><trans-title-group xml:lang="en"><trans-title>Some Remarks on the Phase Transformation of Gas Hydrates in Porous Sediments at Negative Celsius Temperatures</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Гольмшток</surname><given-names>А. Я.</given-names></name><name name-style="western" xml:lang="en"><surname>Golmshtok</surname><given-names>A. Ya.</given-names></name></name-alternatives><bio xml:lang="ru"><p>ГОЛЬМШТОК Александр Яковлевич, кандидат физико-математических наук</p><p>РИНЦ AuthorID: 59679, Scopus AuthorID: 6602613595</p><p>117997, Mocквa, Нахимовский пр-т, д. 36</p></bio><bio xml:lang="en"><p>36 Nakhimovsky Prosp., Moscow 117997</p></bio><email xlink:type="simple">golmshtok@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт океанологии им. П.П. Ширшова РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Shirshov Institute оf Oceanology, Russian Academy of Sciences</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2023</year></pub-date><pub-date pub-type="epub"><day>10</day><month>01</month><year>2024</year></pub-date><volume>16</volume><issue>4</issue><elocation-id>94–106</elocation-id><permissions><copyright-statement>Copyright &amp;#x00A9; Гольмшток А.Я., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Гольмшток А.Я.</copyright-holder><copyright-holder xml:lang="en">Golmshtok A.Y.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://hydrophysics.spbrc.ru/jour/article/view/1261">https://hydrophysics.spbrc.ru/jour/article/view/1261</self-uri><abstract><p>В статье приводится решение задачи о фазовом переходе гидрат метана — метан-газ+лед в пористых гидратсодержащих осадках при отрицательной по Цельсию температуре в среде. Численное решение полученной системы дифференциальных уравнений пьезои теплопроводности позволяет эффективно моделировать изменение давления и температуры во времени и пространстве в среде любой размерности при ее нагреве или декомпрессии. При этом гидратсодержащая среда не подразделяется на области с разными фазовыми состояниями гидрата метана, а рассматривается как единая с характеризующими ее физическими параметрами, изменяющимися по величине в процессе фазового превращения гидратов. На примере решения задачи о термобарическом режиме сферической каверны в массиве газонепроницаемого подземного льда, заполненной гидратом, льдом и свободным метаном-газом, показано, что даже при значительном повышении температуры на поверхности сферы разложение гидрата происходит в крайне тонкой оболочке непосредственно между этой поверхностью и смещенной внутрь сферы фазовой границей. Со временем условия стабильности гидрата устанавливаются заново, но уже при бо́льших давлении газа и температуре среды. Это явление сильно ограниченного разложения гидрата в замкнутом газоизолированном пространстве, тем не менее приводящего к повышению в нем давления, является, по-видимому, основным процессом, обеспечивающим «самоконсервацию» гидратов метана.</p></abstract><trans-abstract xml:lang="en"><p>The article presents a solution to the problem of the phase transition of methane hydrate — methane-gas + ice in porous hydrate-containing sediments at a negative Celsius temperature in the medium. The numerical solution of the resulting system of differential equations of piezoand thermal conductivity makes it possible to effectively simulate the change in pressure and temperature in both time and space in a medium of any dimension during its heating or decompression. In this case, the medium is not subdivided into parts with varying phase states of methane hydrate. Instead, its sediment substance is considered as a single entity, with its physical properties changing in magnitude when the hydrates undergo phase transformation. As an example, the problem of the thermobaric regime of a heating spherical cavern containing ice, hydrate and free methane has been solved. This cavern is situated within a continuous gas-tight underground ice. The solution shows that although the temperature of the sphere surface increases considerably, the decomposition of hydrate only occurs in an extremely thin shell located directly between the surface and the displaced inward phase boundary.Over time, the stability conditions of hydrates establish anew but at a higher gas pressure and medium temperature. This phenomenon of severely limited decomposition of the hydrate in a closed gas-insulated space, nevertheless leading to an increase in pressure in it, is, apparently, the basic process that provides the “self-preservation” of methane hydrates.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>фазовый переход</kwd><kwd>газогидраты</kwd><kwd>самоконсервация</kwd><kwd>осадки</kwd><kwd>пористость</kwd><kwd>давление газа</kwd><kwd>температура</kwd></kwd-group><kwd-group xml:lang="en"><kwd>phase transition</kwd><kwd>gas hydrates</kwd><kwd>self-preservation</kwd><kwd>sediments</kwd><kwd>porosity</kwd><kwd>gas pressure</kwd><kwd>temperature</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Работа выполнена в рамках государственного задания (тема № FMWE-2021–0014).</funding-statement><funding-statement xml:lang="en">The work was carried out within the framework of the state assignment (theme No. FMWE-2021–0014).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Kvenvolden K.A. Gas hydrates — geological perspectives and global change // Reviews of Geophysics. 1993. Vol. 31. Iss. 2. P. 173–187. doi:10.1029/93RG00268</mixed-citation><mixed-citation xml:lang="en">Kvenvolden K.A. Gas hydrates — geological perspectives and global change. Reviews of Geophysics. 1993, 31(2), 173–187. doi:10.1029/93RG00268</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Гинсбург Г.Д., Соловьев В.А. Субмаринные газовые гидраты. СПб.: ВНИИОкеангеология, 1994. 199 с.</mixed-citation><mixed-citation xml:lang="en">Ginsburg G.D., Soloviev V.A. Submarine gas hydrates. St. Petersburg, VNIIOkeangeologia, 1994. 199 p. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Mazurenko L.L., Soloviev V.A. Worldwide distribution of deep-water fluid venting and potential occurrences of gas hydrate accumulations // Geo-Marine Letters. 2003. Vol. 23. P. 162–176. doi:10.1007/S00367-003-0146-X</mixed-citation><mixed-citation xml:lang="en">Mazurenko L.L., Soloviev V.A. Worldwide distribution of deep-water fluid venting and potential occurrences of gas hydrate accumulations. Geo-Marine Letters. 2003, 23/3–4, 162–176. doi:10.1007/S00367-003-0146-X</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Соловьев В.А. Глобальная оценка количества газа в субмаринных скоплениях газовых гидратов // Геология и геофизика. 2002. Т. 43 (7). С. 648–661.</mixed-citation><mixed-citation xml:lang="en">Soloviev V.A. Global assessment of the gas amount in submarine accumulations of gas hydrates. Russian Geology and Geophysics. 2002, 43 (7), 648–661 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Yakushev V.S., Istomin V.A. Gas-hydrates self-preservation effect // Physics and Chemistry of Ice. Supporo: Hokkaido Univ. Press, 1992. P. 112–118.</mixed-citation><mixed-citation xml:lang="en">Yakushev V.S., Istomin V.A. Gas-hydrates self-preservation effect. Physics and chemistry of ice. Supporo, Hokkaido Univ. Press, 1992, 112–118.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Дядин Ю.А. Супрамолекулярная химия: клатратные соединения // Соровский Образовательный Журнал. 1998. № 2. С. 79–88.</mixed-citation><mixed-citation xml:lang="en">Dyadin Yu.A. Supramolecular chemistry: clathrate compounds. Soros Educational Journal. 1998, 2, 79–88 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Истомин В.А., Нестеров А.Н., Чувилин Е.М., Квон В.Г., Решетников А.М. Разложение гидратов различных газов при температурах ниже 273 К // Газохимия. 2008. № 1. С. 30–44.</mixed-citation><mixed-citation xml:lang="en">Istomin V.A., Nesterov A.N., Chuvilin E.M., Kwon V.G., Reshetnikov A.M. Dissociation of hydrates of various gases at temperatures below 273 K. Gasokhimiya. 2008, 1, 30–44 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Sloan E.D., Jr., Koh C. Clathrate hydrates of natural gases. Third edition. N.Y.: CRC Press, 2007. 758 p. doi:10.1201/9781420008494</mixed-citation><mixed-citation xml:lang="en">Sloan E.D., Jr., Koh C. Clathrate Hydrates of Natural Gases. Third edition. N.Y.: CRC Press, 2007. 758 p. doi:10.1201/9781420008494</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Sultan N., Foucher J.P., Cochonat P., Tonnerre T., Bourillet J.F., Ondreas H., Cauquil E., Grauls D. Dynamics of gas hydrate: case of the Congo continental slope // Marine Geology. 2004. Vol. 206. P. 1–18. doi:10.1016/j.margeo.2004.03.005</mixed-citation><mixed-citation xml:lang="en">Sultan N., Foucher J.P., Cochonat P., Tonnerre T., Bourillet J.F., Ondreas H., Cauquil E., Grauls D. Dynamics of gas hydrate: case of the Congo continental slope. Marine Geology. 2004, 206, 1–18. doi:10.1016/j.margeo.2004.03.005</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Handa Y. A calorimetric study of naturally occuring gas hydrates // Industrial &amp; Engineering Chemistry Research. 1988. Vol. 27, N 5. P. 872–874.</mixed-citation><mixed-citation xml:lang="en">Handa Y. (1988b). A calorimetric study of naturally occuring gas hydrates. Industrial &amp; Engineering Chemistry Research. 1988, 27, 5, 872–874.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Нигматулин Р.И., Шагапов В.Ш., Насырова Л.А. «Тепловой удар» в пористой среде, насыщенной газогидратом // Доклады РАН. 1999. Т. 366, № 3. С. 337–340.</mixed-citation><mixed-citation xml:lang="en">Nigmatulin R.I., Shagapov V. Sh., Nasyrova L.A. “Heat impact” in the porous medium saturated by gas hydrates. Doklady RAN. 1999, 366, 3, 337–340 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Kozeny J. Ueber kapillare Leitung des Wassers in Boden // Sitzungsber Akad. Wiss. Wien. 1927. Vol. 136, N 2a. P. 271–306.</mixed-citation><mixed-citation xml:lang="en">Kozeny J. Ueber kapillare Leitung des Wassers in Boden. Sitzungsber Akad. Wiss. Wien. 1927, 136(2a), 271–306.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Carman P. Fluid flow through a granular bed // Transactions of the Institution of Chemical Engineers. 1937. Vol. 15. P. 150–167.</mixed-citation><mixed-citation xml:lang="en">Carman P. Fluid flow through a granular bed. Transactions of the Institution of Chemical Engineers. 1937, 15, 150–167.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Allen P.A., Allen J.R. Basin analysis. Principles and applications. Oxford: Blackwell Scientific Publications, 2005. 549 p.</mixed-citation><mixed-citation xml:lang="en">Allen P.A., Allen J.R. Basin analysis. Principles and applications. Oxford, Blackwell Scientific Publications, 2005, 549 p.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Ландау Л.Д., Лифшиц Е.М. Статистическая физика. М. — Л.: ГИТТЛ, 1940. 223 с.</mixed-citation><mixed-citation xml:lang="en">Landau L.D., Lifshits E.M. Statistical Physics. Moscow–Leningrad, GITTL, 1940, 223 p. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Самарский А.А., Моисеенко Б.Д. Экономическая схема сквозного счета для многомерной задачи Стефана // Журнал вычислительной математики и математической физики. 1965. Т. 5, № 5. С. 816–827.</mixed-citation><mixed-citation xml:lang="en">Samarskii A.A., Moiseyenko B.D. An economic continuous calculation scheme for the stefan multidimensional problem.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Гольмшток А.Я. Многоканальное сейсмическое профилирование, газовые гидраты и моделирование условий образования грязевых вулканов на озере Байкал // Фундаментальная и прикладная гидрофизика. 2016. Т. 9, № 3. С. 18–31.</mixed-citation><mixed-citation xml:lang="en">USSR Computational Mathematics and Mathematical Physics. 1965, 5, 5, 43–58. doi:10.1016/0041-5553(65)90004-2</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">COMSOL Multiphysics®3.5. 2008. License No:1034054</mixed-citation><mixed-citation xml:lang="en">Golmshtok A. Ya. Multichannel seismic profiling, gas hydrates and the numerical simulation of the mud volcanoes formation conditions in Lake Baikal. Fundamental and Applied Hydrophysics. 2016, 9, 3, 18–31 (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">COMSOL Multiphysics®3.5. 2008. License No:1034054</mixed-citation><mixed-citation xml:lang="en">COMSOL Multiphysics®3.5. 2008. License No:1034054</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
