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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">hydrophysics</journal-id><journal-title-group><journal-title xml:lang="ru">Фундаментальная и прикладная гидрофизика</journal-title><trans-title-group xml:lang="en"><trans-title>Fundamental and Applied Hydrophysics</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2073-6673</issn><issn pub-type="epub">2782-5221</issn><publisher><publisher-name>St. Petersburg Research Center of the Russian Academy of Sciences</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.59887/2073-6673.2023.16(4)-5</article-id><article-id custom-type="elpub" pub-id-type="custom">hydrophysics-1258</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ГИДРОФИЗИЧЕСКИЕ И БИОГЕОХИМИЧЕСКИЕ ПОЛЯ И ПРОЦЕССЫ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>HYDROPHYSICAL AND BIOGEOCHEMICAL FIELDS AND PROCESSES</subject></subj-group></article-categories><title-group><article-title>Динамика подкисления Северного Ледовитого океана в 1993–2021 гг. и ее прогноз на конец 21-го века</article-title><trans-title-group xml:lang="en"><trans-title>Arctic Ocean acidification dynamics during 1993–2021 and its projections for the rest of this century</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0000-1225-9579</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Малышева</surname><given-names>А. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Malysheva</surname><given-names>A. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p> </p><p>199034, Санкт-Петербург, 14-я Линия В.О., д. 7</p><p>199034, Санкт-Петербург, Университетская наб., д. 7–9</p></bio><bio xml:lang="en"><p>MALYSHEVA, Aleksandra S.</p><p>РИНЦ AuthorID: 1120098</p><p>WoS ResearcherID HPE-0124-2023</p><p>7 14th Line V.O., St. Petersburg, 199034</p><p>7–9 Universitetskaya Emb., St. Petersburg, 199034</p></bio><email xlink:type="simple">alexandra.malysheva@niersc.spb.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-8290-5043</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Радченко</surname><given-names>Ю. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Radchenko</surname><given-names>I. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>199034, Санкт-Петербург, 14-я Линия В.О., д. 7</p></bio><bio xml:lang="en"><p>RADCHENKO, Iuliia V., Cand.Sc. (Agriculture)</p><p>РИНЦ AuthorID: 1064639</p><p>Scopus AuthorID: 56480302400, WoS ResearcherID AAF-4852-2019</p><p>7 14th Line V.O., St. Petersburg, 199034</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-0889-7855</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Поздняков</surname><given-names>Д. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Pozdnyakov</surname><given-names>D. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p> </p><p>199034, Санкт-Петербург, 14-я Линия В.О., д. 7</p><p>199034, Санкт-Петербург, Университетская наб., д. 7–9</p><p>185910, Петрозаводск, ул. Пушкинская, д. 11</p></bio><bio xml:lang="en"><p>POZDNYAKOV, Dmitry V., Dr. Sc. (Phys.-Math.)</p><p>РИНЦ AuthorID: 179336</p><p>Scopus AuthorID: 56370460300</p><p>7 14th Line V.O., St. Petersburg, 199034</p><p> 7–9 Universitetskaya Emb., St. Petersburg, 199034</p><p>11 Pushkinskaya Str., Petrozavodsk, 185910</p></bio><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Научный фонд «Международный центр по окружающей среде и дистанционному зондированию имени Нансена»; Санкт-Петербургский государственный университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Nansen International Environmental and Remote Sensing Centre; St. Petersburg State University</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Научный фонд «Международный центр по окружающей среде и дистанционному зондированию имени Нансена»</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Nansen International Environmental and Remote Sensing Centre</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Научный фонд «Международный центр по окружающей среде и дистанционному зондированию имени Нансена»; Санкт-Петербургский государственный университет; Карельский научный центр Российской академии наук</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Nansen International Environmental and Remote Sensing Centre; St. Petersburg State University; Karelian Research Centre of the Russian Academy of Sciences</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2023</year></pub-date><pub-date pub-type="epub"><day>09</day><month>01</month><year>2024</year></pub-date><volume>16</volume><issue>4</issue><elocation-id>63–74</elocation-id><permissions><copyright-statement>Copyright &amp;#x00A9; Малышева А.С., Радченко Ю.В., Поздняков Д.В., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Малышева А.С., Радченко Ю.В., Поздняков Д.В.</copyright-holder><copyright-holder xml:lang="en">Malysheva A.S., Radchenko I.V., Pozdnyakov D.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://hydrophysics.spbrc.ru/jour/article/view/1258">https://hydrophysics.spbrc.ru/jour/article/view/1258</self-uri><abstract><p>С использованием данных GLODAP v.2021 и реанализа Global Ocean Biogeochremistry Hidcast GOBH по параметру рН проведены численные оценки динамики подкисления вод Арктического региона (60–90° с.ш.) за период 1993– 2021 гг. и выявлены тенденции подкисления океана (ПО) в свете проекций климата Арктики до конца 2100 года. Будущие тенденции ПО были рассчитаны по моделям CMIP6 для четырех сценариев Shared Socioeconomic Pathways (SSP), в которых представлены разные уровни социально-экономического и сельскохозяйственного развития и эмиссии парниковых газов: SSP1–2.6, SSP2–4.5, SSP3–7.0 и SSP5–8.5.</p><p>Тенденции снижения рН, определенные по in situ данным GLODAP за период 1993–2019 гг. и по данным реанализа за 1993–2021 гг., составили, соответственно: –0,9% (от 8,18–8,11) и –0,7% (от 8,10–8,05). Таким образом, годовая скорость подкисления, оцененная по обоим источникам данных, составила –0,03%.</p><p>На основе метода перцентилей сравнены исторические сценарии pH моделей CMIP6 с данными реанализа, и на этой базе установлены четыре лучшие модели: MPI-ESM1–2-LR, NorESM2-MM, NorESM2-LM и CMCC-ESM2. Результаты прогнозирования указывают на то, что подкисление вод Арктики будет продолжаться до конца этого столетия. Наибольшие темпы снижения рН (–4,9% и –6,2%) соответствуют сценариям SSP3–7.0 и SSP5–8.5, предполагающих повышение средней глобальной температуры на 3,6 °C и 4,4 °C соответственно. Сопоставление полученных результатов с численными оценками динамики рН других авторов свидетельствует, что к концу текущего столетия скорость подкисления (т. е. снижения рН) в Арктике следует ожидать выше, чем в среднем по Мировому океану: разница между каждым из SSP сценариев оказалась равной –0,1.</p></abstract><trans-abstract xml:lang="en"><p>Dynamics of acidification of the Arctic Ocean through 1993–2021 and predictions of further tendencies of this process until the end of 2100 were assessed making use of both the GLODAPv.2021 and the Global Ocean Biogeochremistry Hindcast (GOBH) reanalysis data on pH. The projections of pH were performed by CMIP6 models for four scenarios of rates of socio-economic and agricultural development and emissions of greenhouse gases: SSP1–2.6, SSP2–4.5, SSP3–7.0 and SSP5–8.5.</p><p>The tendencies of pH decline over the last 27 years (1993–2019) as determined from the GLODAP in situ and the reanalysis data over 1993–2021 proved to be, respectively –0.9% (from 8.18–8.11) and –0.7% (from 8.10–8.05). Thus, the annual acidification rate as assessed from both data sources proved to be –0.03%.</p><p>Through the percentile method-based comparison of consistency of historical observation data on pH with GBH model hindcast four best models were identified: MPI-ESM1–2-LR, NorESM2-MM, NorESM2-LM, and CMCC-ESM2. The projection results strongly indicate that the Arctic Ocean acidification will continue till the end of this century. The highest rates of pH decrease (–4.9% and –6.2%) were forecasted, respectively, for scenarios SSP3–7.0 and SSP5–8.5 that implied the global mean temperature increases by 3.6 °C and 4.4 °C, respectively. A comparison of the results obtained with the previously made assessments is indicative that by the end of the current century the rate of acidification (i. e. pH decrease) in the Arctic should be expected to be higher than that averaged over the World Oceans: the difference for each of the SSP scenarios proved to be –0.1.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>Северный Ледовитый океан</kwd><kwd>факторы подкисления воды</kwd><kwd>историческая и текущая динамика pH</kwd><kwd>in situ GLODAP data</kwd><kwd>реанализ</kwd><kwd>модели CMIP6</kwd><kwd>прогноз подкисления и проекции на 2100 г.</kwd></kwd-group><kwd-group xml:lang="en"><kwd>Arctic Ocean</kwd><kwd>water acidification drivers</kwd><kwd>past and ongoing dynamics of pH</kwd><kwd>in situ GLODAP data</kwd><kwd>reanalysis data</kwd><kwd>CMIP6 model simulations</kwd><kwd>acidification hindcast and projections for 2100</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Исследование выполнено при финансовой поддержке Министерства науки и высшего образования Российской Федерации по проекту № 13.2251.21.0006 (Соглашение № 075-10–2021-104 в ГИИС «Электронный бюджет»).</funding-statement><funding-statement xml:lang="en">This study was funded by the Ministry of Science and Higher Education of the Russian Federation under project No. 13.2251.21.0006 (Agreement No. 075-10–2021-104 in the RF “Electronic Budget” System).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Doney S.C., Fabry V.J., Feely R.A., Kleypas J.A. Ocean acidification: The other CO2 problem // Annual Review of Marine Science. 2009. Vol. 1. P. 169–192. doi:10.1146/annurev.marine.010908.163834</mixed-citation><mixed-citation xml:lang="en">Doney S.C., Fabry V.J., Feely R.A., Kleypas J.A. Ocean Acidification: The other CO2 problem. Annual Review of Marine Science. 2009, 1, 169–192. doi:10.1146/annurev.marine.010908.163834</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Xue L., Cai W.-J. Total alkalinity minus dissolved inorganic carbon as a proxy for deciphering ocean acidification mechanisms // Marine Chemistry. 2020. Vol. 222, N 103791. doi:10.1016/j.marchem.2020.103791</mixed-citation><mixed-citation xml:lang="en">Xue L., Cai W.-J. Total alkalinity minus dissolved inorganic carbon as a proxy for deciphering ocean acidification mechanisms. Marine Chemistry. 2020, 222, 103791. doi:10.1016/j.marchem.2020.103791</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Mostofa K.M.G., Liu C.-Q., Zhai W. et al. Reviews and syntheses: Ocean acidification and its potential impacts on marine ecosystems // Biogeosciences. 2016. Vol. 13. P. 1767–1786. doi:10.5194/bg-13–1767–2016</mixed-citation><mixed-citation xml:lang="en">Mostofa K.M.G., Liu C.-Q., Zhai W. et al. Reviews and syntheses: Ocean acidification and its potential impacts on marine ecosystems. Biogeosciences. 2016, 13, 1767–1786. doi:10.5194/bg-13-1767–2016</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Feely R.A., Doney S.C., Cooley S.R. Ocean acidification: Present conditions and future Changes in a high-CO2 world // Oceanography. 2009. Vol. 22, N 4. P. 36–47. doi:10.5670/oceanog.2009.95</mixed-citation><mixed-citation xml:lang="en">Feely R.A., Doney S.C., Cooley S.R. Ocean acidification: Present conditions and future changes in a high-CO2 world. Oceanography. 2009, 22(4), 36–47. doi:10.5670/oceanog.2009.95</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Salisbury J., Green M.L., Hunt C.W., Campbell J.W. Coastal acidification by rivers: A threat to shellfish? // Eos, Transactions American Geophysical Union. 2008. Vol. 89, N 50. P. 513. doi:10.1029/2008EO500001</mixed-citation><mixed-citation xml:lang="en">Salisbury J., Green M.L., Hunt C.W., Campbell J.W. Coastal acidification by rivers: A threat to shellfish? Eos, Transactions American Geophysical Union. 2008, 89, 50, 513. doi:10.1029/2008EO500001</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Yamamoto A., Kawamiya M., Ishida A., Yamanaka Y., Watanabe S. Impact of rapid sea-ice reduction in the Arctic Ocean on the rate of ocean acidification // Biogeosciences. 2012. Vol. 9. P. 2365–2375. doi:10.5194/bg-9-2365–2012</mixed-citation><mixed-citation xml:lang="en">Yamamoto A., Kawamiya M., Ishida A., Yamanaka Y., Watanabe S. Impact of rapid sea-ice reduction in the Arctic Ocean on the rate of ocean acidification. Biogeosciences. 2012, 9, 2365–2375. doi:10.5194/bg-9–2365–2012</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Yang X., Xue L., Li Y. et al. Treated wastewater changes the export of dissolved inorganic carbon and its isotopic composition and leads to acidification in coastal oceans // Environmental Science and Technology. 2018. Vol. 52, N 10. P. 5590–5599. doi:10.1021/acs.est.8b00273</mixed-citation><mixed-citation xml:lang="en">Yang X., Xue L., Li Y. et al. Treated wastewater changes the export of dissolved inorganic carbon and its isotopic composition and leads to acidification in coastal oceans. Environmental Science and Technology. 2018, 52(10), 5590– 5599. doi:10.1021/acs.est.8b00273</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Capelle D.W., Kuzyk Z.A., Papakyriakou T. et al. Effect of terrestrial organic matter on ocean acidification and CO2 flux in an Arctic shelf sea // Progress in Oceanography. 2020. Vol. 185, N 102319. doi:10.1016/j.pocean.2020.102319</mixed-citation><mixed-citation xml:lang="en">Capelle D.W., Kuzyk Z.A., Papakyriakou T. et al. Effect of terrestrial organic matter on ocean acidification and CO2 flux in an Arctic shelf sea. Progress in Oceanography. 2020, 185, 102319. doi:10.1016/j.pocean.2020.102319</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Keeling R.F., Körtzinger A., Gruber N. Ocean deoxygenation in a warming world // Annual Review of Marine Science. 2010. Vol. 2, N 1. P. 199–229. doi:10.1146/annurev.marine.010908.163855</mixed-citation><mixed-citation xml:lang="en">Keeling R.F., Körtzinger A., Gruber N. Ocean deoxygenation in a warming world. Annual Review of Marine Science. 2010, 2, 1, 199–229. doi:10.1146/annurev.marine.010908.163855</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Oschlies A., Brandt P., Stramma L., Schmidtko S. Drivers and mechanisms of ocean deoxygenation // Nature Geoscience. 2018. Vol. 11, N 7. P. 467–473. doi:10.1038/s41561–018–0152–2</mixed-citation><mixed-citation xml:lang="en">Oschlies A., Brandt P., Stramma L., Schmidtko S. Drivers and mechanisms of ocean deoxygenation. Nature Geoscience. 2018, 11, 7, 467–473. doi:10.1038/s41561-018-0152-2</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Riebesell U., Zondervan I., Rost B. et al. Reduced calcification of marine plankton in response to increased atmospheric CO2 // Nature. 2000. Vol. 407. P. 364–367. doi:10.1038/35030078</mixed-citation><mixed-citation xml:lang="en">Riebesell U., Zondervan I., Rost B. et al. Reduced calcification of marine plankton in response to increased atmospheric CO2. Nature. 2000, 407, 364–367. doi:10.1038/35030078</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Albright R., Caldeira L., Hosfelt J. et al. Reversal of ocean acidification enhances net coral reef calcification // Nature. 2016. Vol. 531. P. 362–365. doi:10.1038/nature17155</mixed-citation><mixed-citation xml:lang="en">Albright R., Caldeira L., Hosfelt J. et al. Reversal of ocean acidification enhances net coral reef calcification. Nature. 2016, 531, 362–365. doi:10.1038/nature17155</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Pörtner H.-O. Ecosystem effects of ocean acidification in times of ocean warming: A physiologists view // Marine Ecology Progress Series. 2008. Vol. 373. P. 203–217. doi:10.3354/meps07768</mixed-citation><mixed-citation xml:lang="en">Pörtner H.-O. Ecosystem effects of ocean acidification in times of ocean warming: A physiologists view. Marine Ecology Progress Series. 2008, 373, 203–217. doi:10.3354/meps07768</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Kwiatkowski L., Torres O., Bopp L. et al. Twenty-first century ocean warming, acidification, deoxygenation, and upper-ocean nutrient and primary production decline from CMIP6 model projections // Biogeosciences. 2020. Vol. 17. P. 3439–3470. doi:10.5194/bg-17-3439–2020</mixed-citation><mixed-citation xml:lang="en">Kwiatkowski L., Torres O., Bopp L. et al. Twenty-first century ocean warming, acidification, deoxygenation, and upper-ocean nutrient and primary production decline from CMIP6 model projections. Biogeosciences. 2020, 17, 3439– 3470. doi:10.5194/bg-17-3439–2020</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Zachos J.C., Röhl U., Schellenberg S.A. et al. Rapid acidification of the ocean during the paleocene-eocene thermal maximum // Science. 2005. Vol. 308, N 5728. P. 1611–1615. doi:10.1126/science.1109004</mixed-citation><mixed-citation xml:lang="en">Zachos J.C., Röhl U., Schellenberg S.A. et al. Rapid acidification of the ocean during the paleocene-eocene thermal maximum. Science. 2005, 308, 5728, 1611–1615. doi:10.1126/science.1109004</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Zeebe R.E., Ridgwell A. Past changes in ocean carbonate chemistry // Ocean Acidification, Ed. by Gattuso J.-P. and Hansson L. Oxford University Press, Oxford. 2011. P. 21–40. doi:10.1093/oso/9780199591091.003.0007</mixed-citation><mixed-citation xml:lang="en">Zeebe R.E., Ridgwell A. Past changes in ocean carbonate chemistry. Ocean Acidification. Ed. by Gattuso J.-P. and Hansson L. Oxford University Press, Oxford. 2011, 21–40. doi:10.1093/oso/9780199591091.003.0007</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Raven J., Caldeira K., Elderfield H. et al. Ocean acidification due to increasing atmospheric carbon dioxide. The Royal Society, London, UK, 2005. 68 p.</mixed-citation><mixed-citation xml:lang="en">Raven J., Caldeira K., Elderfield H. et al. Ocean acidification due to increasing atmospheric carbon dioxide. The Royal Society, London, UK, 2005. 68 p.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Jiang Z., Song Z., Bai Y. et al. Remote sensing of Global sea surface pH based on massive underway data and machine learning // Remote Sensing. 2022. Vol. 14, N 10:2366. doi:10.3390/rs14102366</mixed-citation><mixed-citation xml:lang="en">Jiang Z., Song Z., Bai Y. et al. Remote sensing of global sea surface pH based on massive underway data and machine learning. Remote Sensing. 2022, 14(10), 2366. doi:10.3390/rs14102366</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Bindoff N.L., Willebrand J., Artale V. et al. Observations: oceanic climate change and sea level. // Climate change 2007: the physical science basis. Contribution of Working Group I / Ed. by: Solomon S., Qin D., Manning M., Chen Z., Marquis M., Averyt K.B., Tignor M., Miller H.L., Cambridge University Press, Cambridge, 2007. P. 385–428.</mixed-citation><mixed-citation xml:lang="en">Bindoff N.L., Willebrand J., Artale V. et al. Observations: oceanic climate change and sea level. Climate change 2007: The physical science basis. Contribution of Working Group I / Ed. by: Solomon S., Qin D., Manning M., Chen Z., Marquis M., Averyt K.B., Tignor M., Miller H.L. Cambridge University Press, Cambridge. 2007, 385–428.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Sabine C.L., Feely R.A., Gruber N. et al. The oceanic sink for anthropogenic CO2 // Science American Association for the Advancement of Science (AAAS). 2004. Vol. 305, N5682. P. 367–371. doi:10.1126/science.1097403</mixed-citation><mixed-citation xml:lang="en">Sabine C.L., Feely R.A., Gruber N. et al. The Oceanic Sink for Anthropogenic CO2. Science American Association for the Advancement of Science (AAAS). 2004, 305, 5682, 367–371. doi:10.1126/science.1097403</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Orr J.C., Fabry V.J., Aumont O. et al. Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms // Nature. 2005. Vol. 437. P. 681–686. doi:10.1038/nature04095</mixed-citation><mixed-citation xml:lang="en">Orr J.C., Fabry V.J., Aumont O. et al. Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms. Nature. 2005, 437, 681–686. doi:10.1038/nature04095</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Bellerby R., Anderson L., Osborne E. et al. Arctic Ocean acidification: an update // AMAP Assessment 2018: Arctic Ocean Acidification. Arctic Monitoring and Assessment Programme (AMAP), Tromsø, Norway, 2018. 187 p. doi:10.25607/ OBP-783</mixed-citation><mixed-citation xml:lang="en">Bellerby R., Anderson L., Osborne E. et al. Arctic Ocean Acidification: an update. AMAP Assessment 2018: Arctic Ocean Acidification. Arctic Monitoring and Assessment Programme (AMAP), Tromsø, Norway, 2018. 187 p. doi:10.25607/OBP-783</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Will S. The Arctic in an Earth system context: From brake to accelerator of change // Ambio. 2006. Vol. 35, N 4. P. 153–159.</mixed-citation><mixed-citation xml:lang="en">Will S. The Arctic in an Earth system context: From brake to accelerator of change. Ambio. 2006, 35, 4, 153–159.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Lauvset S.K., Lange N., Tanhua T. et al. Global ocean data analysis project version 2.2021 (GLODAPv2.2021) (NCEI Accession 0237935). NOAA National Centers for Environmental Information. Dataset. 2021. URL: https://www.ncei.noaa.gov/access/metadata/landing-page/bin/iso?id=gov.noaa.nodc:0237935 (дата обращения: 26.02.2023). doi:10.25921/ttgq-n825</mixed-citation><mixed-citation xml:lang="en">Lauvset S.K., Lange N., Tanhua T. et al. Global Ocean data analysis project version 2.2021 (GLODAPv2.2021) (NCEI Accession 0237935). NOAA National Centers for Environmental Information. Dataset. 2021. URL: https://www.ncei.noaa.gov/access/metadata/landing-page/bin/iso?id=gov.noaa.nodc:0237935 (дата обращения: 26.02.2023). doi:10.25921/ttgq-n825</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Артемьев В.Е. Геохимия органического вещества в системе река — море. М.: Наука, 1993. 204 с.</mixed-citation><mixed-citation xml:lang="en">Artemiev V.E. Geochemistry of organic matter in the river-sea system. M., Nauka, 1993. 204 p. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Смирнов M.П. Растворенные органические вещества и минерализация речных вод гор с тундрово-таежными типами вертикальной поясности России // Известия Российской академии наук. Серия географическая. 2015. № 5. С. 54–68. doi:10.15356/0373-2444-2015-5-54-68</mixed-citation><mixed-citation xml:lang="en">Smirnov M.P. Dissolved organic matters and mineralization of river water of mountains with tundra-taiga types of vertical zoning in Russia. Izvestiya Rossiiskoi Akademii Nauk, Seriya Geograficheskaya. 2015, 5, 54–68 (in Russian). doi:10.15356/0373-2444-2015-5-54-68</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Rérolle V., Ruiz-Pino D., Rafizadeh M. et al. Measuring pH in the Arctic Ocean: Colorimetric method or SeaFET? // Methods in Oceanography. 2016. Vol. 17. P. 32–49. doi:10.1016/j.mio.2016.05.006</mixed-citation><mixed-citation xml:lang="en">Rérolle V., Ruiz-Pino D., Rafizadeh M. et al. Measuring pH in the Arctic Ocean: Colorimetric method or SeaFET? Methods in Oceanography. 2016, 17, 32–49. doi:10.1016/j.mio.2016.05.006</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Copernicus Marine Environment Monitoring Service: Global ocean biogeochemistry hindcast dataset (GLOBAL_MULTIYEAR_BGC_001_029). URL: https://data.marine.copernicus.eu/product/GLOBAL_MULTIYEAR_BGC_001_029/ (дата обращения: 21.02.2023). doi:10.48670/moi-00019</mixed-citation><mixed-citation xml:lang="en">Copernicus Marine Environment Monitoring Service: Global ocean biogeochemistry hindcast dataset (GLOBAL_MULTIYEAR_BGC_001_029). URL: https://data.marine.copernicus.eu/product/GLOBAL_MULTIYEAR_BGC_001_029/ (дата обращения: 21.02.2023). doi:10.48670/moi-00019</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Earth system grid federation portal. URL: https://esgf-node.llnl.gov (дата обращения: 03.03.2023).</mixed-citation><mixed-citation xml:lang="en">Earth System Grid Federation portal. URL: https://esgf-node.llnl.gov (дата обращения: 03.03.2023).</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">O’Neill B.C., Tebaldi C., Van Vuuren D.P. et al. The scenario model intercomparison project (ScenarioMIP) for CMIP6 // Geoscientific Model Development. 2016. Vol. 9(9). P. 3461–3482. doi:10.5194/gmd-9-3461–2016</mixed-citation><mixed-citation xml:lang="en">O’Neill B.C., Tebaldi C., Van Vuuren D.P. et al. The scenario model intercomparison project (ScenarioMIP) for CMIP6. Geoscientific Model Development. 2016, 9(9), 3461–3482. doi:10.5194/gmd-9-3461–2016</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Masson-Delmotte V., Zhai P., Pirani A. et al. (eds.). IPCC, 2021: Climate Change 2021: The physical science basis. Contribution of working group I to the sixth assessment report of the intergovernmental panel on climate change. Cambridge: Cambridge University Press, 2023. doi:10.1017/9781009157896</mixed-citation><mixed-citation xml:lang="en">Masson-Delmotte V., Zhai P., Pirani A. et al. (eds.). IPCC, 2021: Climate change 2021: The physical science basis. Contribution of working group I to the sixth assessment report of the intergovernmental panel on climate change. Cambridge, Cambridge University Press, 2023. doi:10.1017/9781009157896</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Gnatiuk N., Radchenko I., Davy R., Morozov E., Bobylev L. Simulation of factors affecting Emiliania huxleyi blooms in Arctic and sub-Arctic seas by CMIP5 climate models: model validation and selection // Biogeosciences. 2020. Vol. 17(4). P. 1199–1212. doi:10.5194/bg-17-1199–2020</mixed-citation><mixed-citation xml:lang="en">Gnatiuk N., Radchenko I., Davy R., Morozov E., Bobylev L. Simulation of factors affecting Emiliania huxleyi blooms in Arctic and sub-Arctic seas by CMIP5 climate models: model validation and selection. Biogeosciences. 2020, 17(4), 1199–1212. doi:10.5194/bg-17-1199–2020</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
